Nonlinear frequency response analysis for the diagnosis of carbon monoxide poisoning in PEM fuel cell anodes

被引：0
|
作者：
Thomas Kadyk
Richard Hanke-Rauschenbach
Kai Sundmacher
机构：
[1] Max Planck Institute for Dynamics of Complex Technical Systems,
[2] Otto-von-Guericke University Magdeburg,undefined
来源：
Journal of Applied Electrochemistry | 2011年 / 41卷
关键词：
Polymer electrolyte membrane fuel cell; Nonlinear frequency response analysis; Higher order frequency response function; Carbon monoxide;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Anodic CO poisoning of a PEMFC was analysed by nonlinear frequency response analysis (NFRA) in a differential H2/H2 cell. This special experimental setup excluded potential masking effects, emphasised the main mechanism of CO poisoning and made a simplified modelling approach possible. The main features of CO poisoning were investigated by means of steady state polarisation, EIS and NFRA. The main characteristics of CO poisoning in the NFRA spectra can be used as a “fingerprint” for diagnostic purposes.
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页码：1021 / 1032
页数：11
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