The Coordination and Transformation of Arene Rings by Transition Metal Carbonyl Cluster Complexes

被引:0
|
作者
Sabrina Brait
Stefano Deabate
Selby A. R. Knox
Enrico Sappa
机构
[1] Università di Torino,Dipartimento di Chimica IFM
[2] University of Bristol,School of Chemistry
[3] Università del Piemonte Orientale Amedeo Avogadro,Dipartimento di Scienze e Tecnologie Avanzate
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关键词
transition metal clusters; benzyne ligands; reactivity; cluster-surface analogy; hydrogenation catalysis (homogeneous, solid-gas, heterogeneous);
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摘要
A survey of the synthetic pathways and of the reactivity and catalytic activity of transition metal carbonyl clusters substituted with benzyne (and, for comparison, benzene and diene) ligands is given. Cluster-surface analogies are helpful in gaining an understanding of the homogeneous and heterogeneous catalytic behaviour of the clusters.
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页码:139 / 173
页数:34
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