Synthesis and Complex-Forming Properties of N-Substituted Diazacrown Ethers

被引：0
|
作者：
N. G. Luk'yanenko
S. S. Basok
E. Yu. Kulygina
V. I. Vetrogon
机构：
[1] National Academy of Sciences of Ukraine,Bogatskii Physicochemical Institute
来源：
Russian Journal of General Chemistry | 2003年 / 73卷
关键词：
Nitrogen; Ether; Nitrogen Atom; Macrocycle; Ethoxycarbonylmethyl;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
N-Substituted mono- and diazacrown ether with ethoxycarbonylmethyl, 7-phenyl-3,6-dioxaheptyl, p-methoxy, and p-nitrobenzyl groups in the side chain have been synthesized. Their reactions with alkali and alkaline-earth metals have been studied. Substituents affect the complex-forming ability of the “base” macrocycle by changing the basicity of the nitrogen atoms and coordinating with the complexing ion.
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页码：1919 / 1924
页数：5
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