Determination of the structural features of O-alkyl-S-2-(N,N-dialkylamino) ethyl alkylthiophosphonates from their electron ionization mass spectra

被引：0
|
作者：
A. G. Terentyev
Yu. I. Morozik
I. V. Rybal’chenko
A. V. Dudkin
A. O. Smirnov
G. V. Galyaev
机构：
[1] Military Academy of Nuclear,
[2] Biological,undefined
[3] and Chemical Defence,undefined
[4] Kostroma State Technological University,undefined
来源：
Journal of Analytical Chemistry | 2016年 / 71卷
关键词：
electron ionization mass spectra; negative ion detection; fragmentation; determination of radicals at phosphorus and oxygen atoms;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
It is believed that information about the molecular structure of highly toxic O-alkyl-S-2(N,N-dialkylamino) ethyl alkylthiophosphonates (V-gases) obtained from their EI mass spectra is too insufficient. In particular, the determination of molecular weights and structures of radicals at phosphorus and oxygen atoms causes great difficulties. In this paper, solutions of these problems are proposed.
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页码：1266 / 1274
页数：8
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