Heat Capacities and Thermodynamic Properties of Aqueous SrCl2 Solutions in the Temperature Range from 80 to 320 K

被引:0
|
作者
Qing-Fen Meng
Zhi-Cheng Tan
Ya-Ping Dong
Hai-Tao Feng
Xiao-Huan Wang
Quan Shi
Wu Li
机构
[1] Chinese Academy of Sciences,Qinghai Institute of Salt Lakes
[2] Chinese Academy of Sciences,China Ionic Liquid Laboratory and Thermochemistry Laboratory, Dalian Institute of Chemical Physics
[3] Graduate School of the Chinese Academy of Sciences,undefined
来源
关键词
Heat capacity; SrCl; Adiabatic calorimetry; Phase transitions; Thermodynamic function;
D O I
暂无
中图分类号
学科分类号
摘要
The molar heat capacities of three different concentrations of aqueous SrCl2 solutions, 0.1212, 0.4615 and 1.878 mol⋅kg−1, were measured, using a precision automated adiabatic calorimeter in the temperature range from 80 to 320 K. Solid–liquid phase transitions were observed at 272.83, 270.18 and 255.15 K, respectively, for these three solutions. The molar enthalpies and entropies of the phase transitions were evaluated. The experimental heat capacity data were fitted to polynomial equations, and based on the polynomial equations and thermodynamic relationship, the thermodynamic functions relative to 298.15 K, [HT−H298.15 K] and [ST−S298.15 K], of the three solutions were derived in the range of 80 to 320 K with an interval of 5 K.
引用
收藏
页码:1087 / 1098
页数:11
相关论文
共 50 条
  • [41] Heat Capacity and Standard Thermodynamic Functions of the Wulfenite PbMoO4 over the Temperature Range of (0 to 320) K
    Bissengaliyeva, Mira R.
    Gogol, Daniil B.
    Bekturganov, Nuraly S.
    Taimassova, Shynar T.
    Bespyatov, Michael A.
    Zhusipov, Abdrazak A.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (05): : 1941 - 1945
  • [42] TRIS(HYDROXYMETHYL)AMINOMETHANE - HEAT-CAPACITIES AND THERMODYNAMIC PROPERTIES FROM 5 TO 350 K
    ARVIDSSON, K
    WESTRUM, EF
    JOURNAL OF CHEMICAL THERMODYNAMICS, 1972, 4 (03): : 449 - +
  • [43] BARIUM CHLORIDE HEAT CAPACITIES AND THERMODYNAMIC PROPERTIES FROM 5 DEGREES TO 350 DEGREES K
    GOODMAN, RM
    WESTRUM, EF
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1966, 11 (03): : 294 - &
  • [44] Thermodynamic properties of multicomponent NaCl-LiCl-H2O aqueous solutions at temperature 298.15 K
    El Guendouzi, M
    Benbiyi, A
    Dinane, A
    Azougen, R
    CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2004, 28 (01): : 97 - 103
  • [45] HEAT-CAPACITIES OF 6 ISOMERS OF PENTANOL IN THE TEMPERATURE-RANGE FROM 303 K TO 326 K
    SVOBODA, V
    CEJKA, D
    ZABRANSKY, M
    JOURNAL OF CHEMICAL THERMODYNAMICS, 1994, 26 (02): : 147 - 150
  • [47] Thermodynamic properties of deuterium oxide in the temperature range from 6 to 350 K
    Smirnova, N. N.
    Bykova, T. A.
    Van Durme, K.
    Van Mele, B.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2006, 38 (07): : 879 - 883
  • [48] Heat capacity and thermodynamic properties of GdPO4 in the temperature range 0–1600 K
    V. M. Gurevich
    M. A. Ryumin
    A. V. Tyurin
    L. N. Komissarova
    Geochemistry International, 2012, 50 : 702 - 710
  • [49] Heat capacity and thermodynamic properties of bismuth orthovanadate in the temperature range 356-980 K
    Denisova, L. T.
    Izotov, Ras A. D.
    Chumilina, L. G.
    Kargin, Yu. F.
    Denisov, V. M.
    DOKLADY PHYSICAL CHEMISTRY, 2016, 467 : 41 - 43
  • [50] Partial molar volumes and heat capacities of single ions in aqueous solution over the temperature range 288.15 to 328.15 K
    Hedwig, GR
    Hakin, AW
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (19) : 4690 - 4700