Characteristic features of the radiolysis of water irradiated under strictly fixed conditions and under conditions varying over a small range

被引:0
|
作者
M. L. Lukashenko
S. A. Kabakchi
O. P. Arkhipov
A. I. Milaev
机构
[1] Russian Science Center “Kurchatov Institute,
[2] State Science Center of the Russian Federation-L. Ya. Karpov Scientific-Research Institute of Physical Chemistry,undefined
来源
Atomic Energy | 1999年 / 87卷
关键词
Dose Rate; H202; Elementary Reaction; Stable Product; External Parameter;
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中图分类号
学科分类号
摘要
A qualitative mathematical analysis of the system of differential equations that describes the radiolysis of pure water and water solutions of hydrogen, hydrogen peroxide, and oxygen is performed. It is established that in a closed volume with fixed values of external parameters (dose rate, temperature, and others) a steady state characterized by a stable singular point-type attractor is unavoidably reached. The type of attractor does not depend on the values of the external parameters, i.e., in principle the system possesses self-regulation properties with respect to them. It is shown that under real conditions, when the external parameters cannot be strictly fixed, the existence of a stationary state and a stationary concentration of the products of radiolysis of water are determined not only by the specific values of the external parameters but also by their variation in the time required to establish a stationary state. 3 figures, 1 table, 10 references.
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页码:496 / 504
页数:8
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