On the mechanism of the high-temperature decomposition of azomethane in shock waves

被引：0
|
作者：
N. M. Kuznetsov
Yu. K. Karasevich
Yu. P. Petrov
S. V. Turetskii
机构：
[1] Russian Academy of Sciences,Semenov Institute of Chemical Physics
来源：
Russian Journal of Physical Chemistry B | 2009年 / 3卷
关键词：
Shock Wave; Preexponential Factor; Reaction Coordinate; Azomethane; Observe Activation Energy;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The specifics of the high-temperature unimolecular decomposition of azomethane behind shock waves is theoretically interpreted based on the concept of the anharmonicity of the symmetrical vibration of the molecule. The resonance detuning for the stretching of the two CH3-N bonds during decomposition is estimated. This estimate makes it possible to harmonize the measured and theoretically calculated parameters of the rate constant for azomethane decomposition.
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页码：512 / 513
页数：1
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