Reactions of diols with dimethyl carbonate in the presence of W(CO)6 and Co2(CO)8

被引：0
|
作者：
R. I. Khusnutdinov
N. A. Shchadneva
Yu. Yu. Mayakova
机构：
[1] Russian Academy of Sciences,Institute of Petrochemistry and Catalysis
来源：
Russian Journal of Organic Chemistry | 2014年 / 50卷
关键词：
Diol; Diethylene Glycol; Dimethyl Carbonate; Tertiary Alcohol; Glycol Dimethyl Ether;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Dimethoxyalkanes and dimethyl alkanediyl biscarbonates were synthesized by reactions of diols with dimethyl carbonate in the presence of tungsten and cobalt carbonyls. Optimal reactant and catalyst ratios and reaction conditions were found to ensure selective formation of dimethoxyalkanes or dimethyl alkanediyl biscarbonates.
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页码：948 / 952
页数：4
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