Hydrothermal synthesis and structural characterization of a new 3D chiral coordination polymer [Cd2(C4H4O6)2]n

被引：0
|
作者：
Y. E. Du
Z. B. Han
机构：
[1] Liaoning University,College of Chemistry
来源：
Russian Journal of Coordination Chemistry | 2011年 / 37卷
关键词：
Coordination Chemistry; Coordination Polymer; Hydrothermal Synthesis; Binaph Thyl; Cinchonidine;
D O I：
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中图分类号：
学科分类号：
摘要：
A new chiral coordination polymer [Cd2(C4H4O6)2]n (I) has been synthesized and characterized by elemental analysis, IR, and X-ray single-crystal diffraction. The X-ray diffraction analysis reveals that I crystallizes in the orthorhombic system, space group P212121. The adjacent Cd(1) and Cd(2) centers are linked by one tartrate ligand through tridentate coordination to form a dimer. The dimer is further connected to the other dimer via tartrate ligands to construct an infinite three-dimensional (3D) coordination polymer. The unit cell parameters for I: a = 7.4984(17), b = 7.9106(18), c = 19.560(4) Å, V = 1160.2(5) Å3, Z = 4.
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页码：506 / 510
页数：4
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