Syntheses, Structures and Properties of Two 2D Transition Metal Coordination Polymers Based on Oxalate and Two Types of N-donor Auxiliary Ligands

被引：0

作者：

Ju-Wen Zhang

Li-Li Hou

Wei Zhao

Jing-Jing Huang

Xiu-Li Wang

机构：

[1] Bohai University,Department of Chemistry

[2] Liaoning Province Silicon Materials Engineering Technology Research Center,undefined

来源：

Journal of Inorganic and Organometallic Polymers and Materials | 2013年 / 23卷

关键词：

Oxalate; Bis(benzimidazole) ligand; Bis-pyridyl-bis-amide ligand; Coordination polymer; Electrochemical property; Luminescent property;

D O I：

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学科分类号：

摘要：

Two new two-dimensional (2D) metal–organic coordination polymers [Co(ox)(bbbm)]·H2O (1) and [Cu(ox)(bppdca)]·2H2O (2) (H2ox = oxalic acid, bbbm = 1,1-(1,4-butanediyl)bis-1H-benzimidazole and bppdca = N,N′-bis(pyridin-3-yl)-2,6-pyridinedicarboxamide) were synthesized under hydrothermal conditions and structurally characterized. Both 1 and 2 exhibit a 2D four-connected network formed by the CoII/CuII ions as four-connected nodes; and, the ox anions and bbbm/bppdca ligands as linkers with a (44.62) topology as determined by single crystal X-ray diffraction. In addition, the thermal stability, electrochemical and luminescent properties for 1 and 2 were investigated.

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页码：1001 / 1007

页数：6

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