Assembly of Two Coordination Polymers Based on the Flexible Carboxylate and N-Donor Ligands with Polycatenane Characterization: Syntheses, Crystal Structures, and Luminescent Properties

被引：3
|
作者：
Du, Jie [1 ,2 ]
Zou, Guanglong [2 ]
Guo, Feng [3 ]
机构：
[1] Guiyang Univ, Coll Chem & Mat Engn, Guiyang 550005, Peoples R China
[2] Guizhou Minzu Univ, Sch Chem & Environm Sci, Guiyang 550025, Peoples R China
[3] Dezhou Univ, Key Lab Coordinat Chem & Funct Mat Univ Shandong, Dezhou 253023, Shandong, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2016年 / 642卷 / 11-12期
基金：
中国国家自然科学基金;
关键词：
Topology; Flexible carboxylate; N-donor; Luminescence; METAL-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; SERIES; COMPLEXES; MOTIFS; ACID; POLYROTAXANE; TOPOLOGIES; DIVERSITY; ZN(II);
D O I：
10.1002/zaac.201600067
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The coordination polymers {[Zn-3(bcp)(2)(bip)(OH)(2)]2H(2)O}(n) (1) and {[Cd(bcp)(bpa)]2H(2)O}(n) (2) [H(2)bcp = 1,3-bis(4-carboxy-phenoxy) propane, bmp = 1,4-bis(2-methylimidazol-3-ium-1-yl) biphenyl, and bpa = bis(4-pyridyl) amine] based on the flexible carboxylate and N-donor ligands were synthesized and characterized. The structures were determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, IR spectroscopy, and XPRD. Complex 1 displays a 2D2D threefold interpenetrated network and complex 2 shows a 1D+1D2D interpenetrated network. Furthermore, the luminescent properties of complexes 1 and 2 were investigated.
引用
收藏
页码：704 / 708
页数：5
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