Hydrochlorinated derivatives of syndiotactic 1,2-polybutadiene

被引：0
|
作者：
A. B. Glazyrin
M. I. Abdullin
R. R. Muslukhov
V. A. Kraikin
机构：
[1] Bashkir State University,Institute of Organic Chemistry, Ufa Research Center
[2] Russian Academy of Sciences,undefined
来源：
Polymer Science Series A | 2011年 / 53卷
关键词：
Polymer Science Series; Chlorine Atom; Intrinsic Viscosity; Hydrogen Chloride; Polybutadiene;
D O I：
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中图分类号：
学科分类号：
摘要：
Chlorine-containing polymeric products with a degree of functionalization of up to 70% are synthesized through the hydrochlorination of syndiotactic 1,2-polybutadiene via carbon-carbon double bonds. The introduction of chlorine atoms into polydiene units causes substantial changes in the viscosity of polymer solutions, the flowability of the polymer melt, the glass-transition and flow temperatures, and the thermal stability of polymers. The hydrochlorinated derivatives of syndiotactic 1,2-polybutadiene demonstrate good adhesion with respect to steel and can be used in adhesive compositions.
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页码：110 / 115
页数：5
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