Effect of pressure on the activity and selectivity of cobalt-zeolite catalysts for the synthesis of hydrocarbons from CO and H2

被引：0
|
作者：
A. L. Lapidus
V. S. Budtsov
O. L. Eliseev
A. S. Volkov
机构：
[1] Russian Academy of Sciences,Zelinsky Institute of Organic Chemistry
[2] Sunfuel Ltd.,undefined
来源：
Solid Fuel Chemistry | 2008年 / 42卷
关键词：
Zeolite; Zeolite Catalyst; Liquid Hydrocarbon; Solid Fuel Chemistry; Heavy Fraction;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The effect of pressure (0.5–2.5 MPa) on the synthesis of hydrocarbons from CO and H2 on Co-zeolite catalysts in a fixed-bed flow reactor was studied. It was found that productivity and selectivity for liquid hydrocarbons increased with pressure, whereas the selectivity of methane formation did not increase. The isoparaffin content of the products of catalysis was inversely proportional to the amount of heavy fractions in the products.
引用
收藏
页码：354 / 357
页数：3
相关论文
共 50 条
  • [41] INFLUENCE OF PHYSIOCHEMICAL CHARACTERISTICS ON PROPERTIES OF CO CATALYSTS FOR SYNTHESIS OF HYDROCARBONS FROM CO AND H2
    LAPIDUS, AL
    BUDTSOV, VS
    SAVOSTYANOV, AP
    KRYLOVA, AY
    MEZHOV, VD
    BAKUN, VG
    PETROLEUM CHEMISTRY, 1991, 31 (05) : 623 - 626
  • [42] SYNTHESIS OF HYDROCARBONS FROM CO AND H2 IN THE PRESENCE OF SUPPORTED CO CATALYSTS MODIFIED BY PALLADIUM
    LAPIDUS, AL
    KRYLOVA, AY
    KOZLOVA, GV
    KONDRATEV, LT
    MYSHENKOVA, TN
    BABENKOVA, LV
    KULEVSKAYA, YG
    SOMINSKII, SD
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1990, 39 (03): : 452 - 455
  • [43] SYNTHESIS OF HYDROCARBONS AND ALCOHOLS FROM CO AND H2 IN THE PRESENCE OF CO-RH CATALYSTS
    LAPIDUS, AL
    NOVAK, Z
    SAELEV, MM
    LYUKKE, B
    ZIMMERMAN, T
    PIROZHKOV, SD
    MANEK, KE
    SOMINSKII, SD
    RAR, LF
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1990, 39 (08): : 1545 - 1547
  • [44] Experience in introducing a cobalt catalyst technology for the synthesis of hydrocarbons from CO and H2
    Narochnyi G.B.
    Yakovenko R.E.
    Savost’yanov A.P.
    Bakun V.G.
    Catalysis in Industry, 2016, 8 (2) : 139 - 144
  • [45] Effect of the nature of the support of a cobalt catalyst on the synthesis of hydrocarbons from CO, H2, and C2H4
    A. L. Lapidus
    A. Yu. Krylova
    Ya. V. Mikhailova
    L. V. Sineva
    A. B. Erofeev
    Solid Fuel Chemistry, 2011, 45
  • [46] Effect of the Nature of the Support of a Cobalt Catalyst on the Synthesis of Hydrocarbons from CO, H2, and C2H4
    Lapidus, A. L.
    Krylova, A. Yu.
    Mikhailova, Ya. V.
    Sineva, L. V.
    Erofeev, A. B.
    SOLID FUEL CHEMISTRY, 2011, 45 (02) : 71 - 80
  • [47] EFFECT OF OXIDES ON THE ACTIVITY OF CO-CARBONYL CATALYSTS FOR HYDROCARBON SYNTHESIS FROM CO AND H2
    LAPIDUS, AL
    KRYLOVA, AY
    KOZLOVA, GV
    KONDRATEV, LT
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1989, 38 (11): : 2226 - 2229
  • [48] SYNTHESIS OF HYDROCARBONS FROM CARBON-MONOXIDE .2. ACTIVITY AND SELECTIVITY OF BIMETALLIC CATALYSTS WITH COBALT
    VILLEGER, P
    BARRAULT, J
    BARBIER, J
    LECLERCQ, G
    MAUREL, R
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE PARTIE I-PHYSICOCHIMIE DES SYSTEMES LIQUIDES ELECTROCHIMIE CATALYSE GENIE CHIMIQUE, 1979, (9-10): : 413 - 418
  • [49] INFLUENCE OF THE MODIFYING CATION NATURE ON ACTIVITY AND SELECTIVITY OF HYDROCARBON FROM CO AND H2 SYNTHESIS CO/SIO2 CATALYSTS
    PAVLENKO, NV
    LUNYEV, NK
    STRUZHKO, VL
    KOSENKO, EI
    TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA, 1992, 28 (03): : 197 - 201
  • [50] Inverse isotope effect in the Co catalyzed synthesis of hydrocarbons from CO and H2
    Shi, Buchang
    Jin, Chunfen
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
12345