Limitations of the Wilson model for describing excess molar heat capacities of binary solutions

被引:0
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作者
V. M. Raeva
S. K. Klyuchikov
A. K. Frolkova
L. A. Serafimov
机构
[1] Lomonosov State Academy of Fine Chemical Technology,
关键词
Binary Solution; Bromobenzene; Excess Function; Excess Heat Capacity; Geometric Type;
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学科分类号
摘要
The forms of the concentration dependences of the excess molar heat capacities of 150 homogeneous binary solutions were analyzed. Limitations of the Wilson model as a tool for reproducing the local trends of these dependences, including those related to temperature changes, were revealed.
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页码:775 / 784
页数:9
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