Limitations of the Wilson model for describing excess molar heat capacities of binary solutions

被引：0

作者：

V. M. Raeva

S. K. Klyuchikov

A. K. Frolkova

L. A. Serafimov

机构：

[1] Lomonosov State Academy of Fine Chemical Technology,

来源：

Russian Journal of Physical Chemistry A | 2009年 / 83卷

关键词：

Binary Solution; Bromobenzene; Excess Function; Excess Heat Capacity; Geometric Type;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The forms of the concentration dependences of the excess molar heat capacities of 150 homogeneous binary solutions were analyzed. Limitations of the Wilson model as a tool for reproducing the local trends of these dependences, including those related to temperature changes, were revealed.

引用

页码：775 / 784

页数：9

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