Hydrogeochemical characteristics and solute sources of groundwater in the Yuhengbei mining area, Shaanxi Province, China

In mining areas, groundwater resources are crucial for providing drinking water, as well as water needed for plant growth and mining. The Yuhengbei mining area is situated in arid and semi-arid areas in Western China. As there are a number of large-scale mining fields in the area, their exploitation may affect both the quality and quantity of groundwater. The hydraulic connection between aquifers directly determines whether deep coal mining activities affect water quality in shallow aquifers. This study investigates the hydrogeochemical characteristics and the solute sources of groundwater (including surface water, Quaternary water, water from Cretaceous and Jurassic coal strata aquifer) in the Yuhengbei mining area. The study uses conventional, multivariate statistical analysis, and dissolved organic matter (DOM) analysis. The results suggest that all water samples were slightly alkaline, while the water from the shallow aquifers (surface water, Quaternary and Cretaceous aquifers) was predominantly of the HCO3-Ca type. Furthermore, the groundwater in the deep Jurassic aquifer was mostly of the SO4-Na type. Major ion and DOM concentrations appeared to decrease with increasing aquifer depth. Moreover, the groundwater circulation is regulated by natural processes. Namely, rock weathering was the main mechanism controlling the chemical constituents of groundwater in the shallow aquifers, while groundwater quality in deep aquifers was mainly governed by the dissolution of evaporation. Water–rock interaction and cation exchange were the main mechanisms controlling the chemical constituents of groundwater. The R-mode HCA revealed that natural processes controlled the chemical composition of groundwater, as well as that the evolution of groundwater is primarily controlled by the nature of the geological structures and the local hydrogeological conditions. The TOC and UV254 results suggest that the coal strata aquifer had a weak hydraulic connection with the overlying aquifers. The DOM was mainly derived from autogenous biological sources. Based on the indicator values, the hydraulic connection between the deep aquifers and the upper shallow aquifers was weak overall. These results show that in this area, although drinking water and irrigation water come predominantly from shallow groundwater, mining activities temporarily have little impact on the quality of shallow groundwater. Better understanding hydrogeochemical characteristics and formation mechanisms will provide a technical basis for local groundwater management and support the sustainable use of water resources.