Influence of Self-Heating on the Kinetics of an Exothermal Reaction under Isothermal Conditions

被引：0
|
作者：
Korsunskiy, B. L. [1 ,2 ]
Samoilenko, N. G. [1 ]
机构：
[1] Russian Acad Sci, Fed Res Ctr Problems Chem Phys & Med Chem, Chernogolovka, Russia
[2] Russian Acad Sci, Semenov Inst Chem Phys, Moscow, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B | 2024年 / 18卷 / 01期
关键词：
kinetics; exothermal reaction; heat transfer;
D O I：
10.1134/S1990793124010123
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
Estimates are made showing that when an exothermal reaction proceeds in an isothermal medium (in a thermostat), self-heating occurs, whose values are determined by the competition between the processes of heat input and heat removal. Relationships are obtained that make it possible to estimate the deviation of the observed values of the kinetic parameters from the true values and to reveal the influence of various parameters on these deviations.
引用
收藏
页码：132 / 135
页数：4
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