Performance optimization of bimetallic Co3(PO4)2@Ni3(PO4)2 electrodes for supercapacitive applications

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作者
Raphael M. Obodo
Joseph N. Aniezi
Joy N. Egbucha
Philips C. Oleji
Ugochukwu C. Elejere
Chimezie U. Eze
Chibuike Ononogbo
I. Ahmad
M. Maaza
机构
[1] University of Agriculture and Environmental Sciences,Department of Physics
[2] University of Agriculture and Environmental Sciences,Department of Chemistry
[3] University of Agriculture and Environmental Sciences,Department of Computer Science
[4] University of Nigeria,Department of Physics and Astronomy
[5] Federal College of Education,Department of Physics
[6] Federal University of Technology,Department of Physics
[7] University of Agriculture and Environmental Sciences,Department of Mechanical Engineering
[8] Quaid-I-Azam University,National Center for Physics
[9] Northwestern Polytechnical University,NPU
[10] Nanosciences African Network (NANOAFNET) iThemba LABS-National Research Foundation,NCP Joint International Research Center On Advanced Nanomaterials and Defects Engineering
[11] UNESCO-UNISA Africa Chair in Nanosciences/Nanotechnology,College of Graduate Studies
[12] University of South Africa (UNISA),undefined
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The recent high rises in energy crisis worldwide have prompted scientists and scholars to incessantly research on modern energy conversion and storage devices. In this work, we employed the service of composites of transition bimetallic phosphates in fabrication of electrodes for usages in supercapacitors. The morphology of these electrodes showcase a mixture of leaf, sphere and platelet nanoparticles spread evenly on the surface of the substrate with respect to precursor ratio variations. These fabricated electrodes indicated appreciable crystalline nature from XRD results. Various band gap energies of these electrodes are very low, supporting their excellent electrochemical performance. The excellent charge storage performance of various electrodes were evident from the electrochemical studies and indicate that Co3(PO4)2@Ni3(PO4)2 electrodes are potential electrodes for supercapacitors applications. Various electrochemical results clearly designated that bimetallic Co3(PO4)2@Ni3(PO4)2 composites formation improved electrodes supercapacitive performance and cycle stability.
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