Synthesis, Crystal Structure, and Luminescent Properties of Two ZnII/CdII Coordination Polymers Based on 1,4-Bis(pyridine-3-Ylmethoxy)benzene

被引:0
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作者
J. Song
J. Liu
J. Shi
J. W. Ji
R. Wu
J. F. Lu
Q. Zhang
机构
[1] Shaanxi University of Technology,Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science
关键词
hydrothermal synthesis; crystal structure; luminescent property; thermal stability;
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摘要
Two polymeric frameworks, [Zn(Dpb)(Oba)]n (Ι) and [Cd(Dpb)(2,6-Pda)H2O]n · nH2O (II) (Dpb = 1,4-bis(pyridin-3-ylmethoxy)benzene, H2Oba = 4,4'-oxybis(benzoic acid), 2,6-H2Pda = 2,6-pyridyl-dicarboxylate), have been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction method (CIF files CCDC 1488269 (Ι), 1488270 (II)). Complex Ι is a 2D layer structure, which is constructed from 1D double chain. Complex II is a 1D chain. The luminescent properties of Ι, II have been investigated with fluorescent spectra in the solid state, I and II displayed a strong fluorescent emission at room temperature.
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页码:685 / 692
页数:7
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