Synthesis of new charge-compensated cobalt bis(1,2-dicarbollide) derivatives

被引：0
|
作者：
I. D. Kosenko
I. A. Lobanova
Z. A. Starikova
V. I. Bregadze
机构：
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
来源：
Russian Chemical Bulletin | 2013年 / 62卷
关键词：
cobalt bis(1,2-dicarbollide); charge-compensated derivatives; 8,8′-μ-iodo-3-; -3-cobalta-bis(1,2-dicarba-; -dodecaborane); reactivity; X-ray diffraction studies;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
New hetero-substituted charge-compensated cobalt bis(1,2-dicarbollide) derivatives were synthesized by the reaction of 8,8′-μ-iodo-3-commo-3-cobalta-bis(1,2-dicarba-closo-dodecaborane) [8,8′-μ-I-3,3′-Co(1,2-C2B9H10)2] with 1,4-thioxane, pyridine N-oxide, and tetrahydropyran. X-ray diffraction studies showed that the 8′-iodo-8-(pyridiniumoxy)eucosahydro-1,1′,2,2′-tetracarba-3-commo-cobalta-closo-tricosaborate molecule has the gauche-conformation (the substituents are turned with respect to each other by 69.2°). The positive charge is predominantly localized on the N(Py) atom.
引用
收藏
页码：1914 / 1918
页数：4
相关论文
共 50 条
  • [11] Charge-compensated nido-carborane derivatives in the synthesis of iron(<sc>ii</sc>) bis(dicarbollide) complexes
    Stogniy, Marina Yu.
    Anufriev, Sergey A.
    Bogdanova, Ekaterina V.
    Gorodetskaya, Nadezhda A.
    Anisimov, Alexei A.
    Suponitsky, Kyrill Yu.
    Grishin, Ivan D.
    Sivaev, Igor B.
    DALTON TRANSACTIONS, 2024, 53 (07) : 3363 - 3376
  • [12] Direct and facile synthesis of carbon substituted alkylhydroxy derivatives of cobalt bis(1,2-dicarbollide), versatile building blocks for synthetic purposes
    Gruener, Bohumir
    Svec, Petr
    Sicha, Vaclav
    Padelkova, Zdenka
    DALTON TRANSACTIONS, 2012, 41 (25) : 7498 - 7512
  • [13] New B-substituted derivatives of m-carborane, p-carborane, and cobalt bis(1,2-dicarbollide) anion
    Beletskaya, IP
    Bregadze, VI
    Ivushkin, VA
    Petrovskii, PV
    Sivaev, IB
    Sjöberg, S
    Zhigareva, GG
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (18) : 2920 - 2929
  • [14] Synthesis of 1,4-disubstituted 1,2,3-triazoles based on cobalt bis(1,2-dicarbollide)
    Kosenko, I. D.
    Lobanova, I. A.
    Chekulaeva, L. A.
    Godovikov, I. A.
    Bregadze, V. I.
    RUSSIAN CHEMICAL BULLETIN, 2013, 62 (02) : 497 - 503
  • [15] Synthesis of 1,4-disubstituted 1,2,3-triazoles based on cobalt bis(1,2-dicarbollide)
    I. D. Kosenko
    I. A. Lobanova
    L. A. Chekulaeva
    I. A. Godovikov
    V. I. Bregadze
    Russian Chemical Bulletin, 2013, 62 : 497 - 503
  • [16] Reactions of bromine-bridged cobalt bis(1,2-dicarbollide) anion with arenes and nucleophiles
    Kosenko, Irina
    Lobanova, Irina
    Ananyev, Ivan
    Laskova, Julia
    Semioshkin, Andrey
    Bregadze, Vladimir
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 818 : 58 - 67
  • [17] Boron(8) substituted nitrilium and ammonium derivatives, versatile cobalt bis(1,2-dicarbollide) building blocks for synthetic purposes
    Sicha, Vaclav
    Plesek, Jaromir
    Kvicalova, Magdalena
    Cisarova, Ivana
    Gruener, Bohumir
    DALTON TRANSACTIONS, 2009, (05) : 851 - 860
  • [18] Transition metal complexes with charge-compensated dicarbollide ligands
    Timofeev, Sergey V.
    Sivaev, Igor B.
    Prikaznova, Elena A.
    Bregadze, Vladimir I.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 751 : 221 - 250
  • [19] Nickel(IV) bis(3)-1,2-dicarbollide) as an acceptor molecule in the synthesis of electrically conducting charge transfer complexes
    Organometallics, 2 (666):
  • [20] Chemistry of cobalt bis(1,2-dicarbollide) ion; the synthesis of carbon substituted alkylamino derivatives from hydroxyalkyl derivatives via methylsulfonyl or p-toluenesulfonyl esters
    Nekvinda, Jan
    Svehla, Jaroslav
    Cisarova, Ivana
    Gruener, Bohumir
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2015, 798 : 112 - 120
12345