Motif of the three-layered close packing of cluster anions in [RhPy4Cl2]4[Re6S8(CN)6]·1.5H2O

被引：0
|
作者：
E. A. Shusharina
K. V. Yusenko
N. V. Kuratieva
I. A. Baidina
S. A. Gromilov
机构：
[1] Novosibirsk State University,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Russian Academy of Sciences,undefined
来源：
Journal of Structural Chemistry | 2008年 / 49卷
关键词：
X-ray analysis; rhodium; rhenium; cluster; crystal chemistry;
D O I：
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学科分类号：
摘要：
[RhPy4Cl2]4[Re6S8(CN)6]·1.5H2O (Py is pyridine) was investigated by X-ray analysis. In the cluster anion, the Re-Re distances vary from 2.6063(2) Å to 2.6125(2) Å. For two crystallographically independent complex cations, the distances are 〈Rh-N〉 2.060 Å and 〈Rh-Cl〉 2.336 Å. The motif of the three-layered close packing was found; the [Re6S8(CN)6]4− anions follow the vertices of a rhombohedron with the parameters ac ≈ 15.5 Å and αc ≈ 61°.
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页码：375 / 377
页数：2
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