Pseudohexagonal motif of the arrangement of compex anions in the structure of [Ru(NH3)5Cl]2[Re6S8(CN)6]·3H2O

被引：0
|
作者：
K. V. Yusenko
I. A. Baidina
E. A. Shusharina
S. A. Gromilov
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,undefined
来源：
Journal of Structural Chemistry | 2008年 / 49卷
关键词：
X-ray diffraction analysis; X-ray phase analysis; ruthenium; rhenium; crystal chemistry; chloropentammine;
D O I：
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摘要：
The [Ru(NH3)5Cl]2[Re6S8(CN)6]·3H2O salt was obtained; its crystal structure was analyzed: a = 10.7713(9) Å, b = 13.9602(11) Å, c = 14.7956(11) Å, α = 91.961(3)°, β = 109.985(3)°, γ = 110.030(3)°, V = 1935.3(3) Å3, space group P1¯, Z = 2, dcalc = 3.441 g/cm3. In the cluster anion, the Re-Re distances lie in the range from 2.594 Å to 2.612 Å. For two crystallographically independent complex cations, Ru-Nav is 2.105 Å, and Ru-Clav 2.329 Å. A pseudohexagonal motif of the structure was found.
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页码：170 / 174
页数：4
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