Synthesis, properties, and thermal decomposition products of [Ru(NH3)5Cl][PtCl6] and [Ru(NH3)5Cl]2[PtCl6]Cl2

被引：8
|
作者：
Martynova, S. A.
Yusenko, K. V.
Korol'kov, I. V.
Gromilov, S. A.
机构：
[1] Novosibirsk State Univ, Novosibirsk 630090, Russia
[2] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 33卷 / 07期
关键词：
D O I：
10.1134/S1070328407070093
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The double complex salts [Ru(NH3)(5)Cl][PtCl6] (I) and [Ru(NH3)(5)Cl](2)[PtCl6]Cl-2 (II) were synthesized and studied by X-ray diffraction. They were found to be isostructural to the previously synthesized [Rh(NH3)(5)Cl][OsCl6] and [Ir(NH3)(5)Cl](2)[PtCl6]Cl-2. The thermolysis of the complexes in the atmosphere of hydrogen and helium was studied by the powder X-ray diffraction analysis. The product of the salt I thermolysis is a single-phase solid solution Ru0.5Pt0.5 (a = 3.857(3) angstrom), the thermolysis of salt II results in a double-phase metallic powder.
引用
收藏
页码：530 / 534
页数：5
相关论文
共 50 条
  • [1] Synthesis, properties, and thermal decomposition products of [Ru(NH3)5Cl][PtCl6] and [Ru(NH3)5Cl]2[PtCl6]Cl2
    S. A. Martynova
    K. V. Yusenko
    I. V. Korol’kov
    S. A. Gromilov
    [J]. Russian Journal of Coordination Chemistry, 2007, 33 : 530 - 534
  • [2] Synthesis and crystal structure of [Rh(NH3)5Cl]2[PtCl6] Cl2
    Yusenko, KV
    Gromilov, SA
    Korenev, SV
    Baidina, IA
    Korol'kov, IV
    Drebushchak, TN
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 43 (04) : 697 - 699
  • [3] Synthesis and Crystal Structure of [Rh(NH3)5Cl]2[PtCl6]Cl2
    K. V. Yusenko
    S. A. Gromilov
    S. V. Korenev
    I. A. Baidina
    I. V. Korol'kov
    T. N. Drebushchak
    [J]. Journal of Structural Chemistry, 2002, 43 : 697 - 699
  • [4] COMPARISONS OF PI-BONDING AND HYDROGEN-BONDING IN ISOMORPHOUS COMPOUNDS - (CR(NH3)5CL)CL2, (CO(NH3)5CL)CL2, (RH(NH3)5CL)CL2, (IR(NH3)5CL)CL2, (RU(NH3)5CL)CL2, (OS(NH3)5CL)CL2
    HAMBLEY, TW
    LAY, PA
    [J]. INORGANIC CHEMISTRY, 1986, 25 (25) : 4553 - 4558
  • [5] Study of complex salts [Ru(NH3)5Cl][PtCl4] and [Ru(NH3)5Cl][PdCl4] • H2O and the products of their thermal decomposition
    Shubin, YV
    Korenev, SV
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2002, 47 (11) : 1663 - 1667
  • [6] Double complex salts with [Ru(NH3)5Cl]2+ cation and [OsCl6]2− anion: Synthesis and properties. Crystal structure of [Ru(NH3)5Cl]2[OsCl6]Cl2
    I. V. Korol’kov
    S. A. Martynova
    K. V. Yusenko
    S. V. Korenev
    [J]. Russian Journal of Inorganic Chemistry, 2010, 55 : 1347 - 1351
  • [7] Synthesis and properties of [Rh(NH3)5Cl]PtCl4]
    Korenev, SV
    Venediktov, AB
    Yusenko, KV
    Shubin, YV
    [J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2000, 26 (05) : 358 - 360
  • [8] Double Complex Salts with [Ru(NH3)5Cl]2+ Cation and [OsCl6]2- Anion: Synthesis and Properties. Crystal Structure of [Ru(NH3)5Cl]2[OsCl6]Cl2
    Korol'kov, I. V.
    Martynova, S. A.
    Yusenko, K. V.
    Korenev, S. V.
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2010, 55 (09) : 1347 - 1351
  • [9] THE INTERACTION OF [RU(NH3)5CL]2+ AND [RU(NH3)6]3+ IONS WITH DNA
    TSELEPIKALOULI, E
    KATSAROS, N
    [J]. JOURNAL OF INORGANIC BIOCHEMISTRY, 1989, 37 (04) : 271 - 282
  • [10] DERIVATOGRAPHIC THERMOANALYSIS OF [CO(NH3)5CL]CL2
    JASIM, F
    HAMID, K
    [J]. THERMOCHIMICA ACTA, 1989, 145 : 189 - 194
12345