X-Ray photoelectron spectra of iron trimethylacetate complexes

被引：0
|
作者：
A. V. Naumkin
T. M. Ivanova
A. V. Shchukarev
A. A. Sidorov
M. A. Kiskin
V. M. Novotortsev
I. L. Eremenko
机构：
[1] Russian Academy of Sciences,Nesmeyanov Institute of Organoelement Compounds
[2] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[3] St Petersburg State University,undefined
来源：
Russian Journal of Inorganic Chemistry | 2008年 / 53卷
关键词：
Pivalic Acid; Trimethylacetate; Trimethylacetate Complex; Sat1 Sat1; Strong Satellite Line;
D O I：
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中图分类号：
学科分类号：
摘要：
Bi-, tri-, and hexanuclear iron(II,III) trimethylacetate complexes were studied by X-ray photoelectron spectroscopy. The compounds differed in the number of Fe-O and Fe-N coordination bonds. The Fe 2p, Fe 3p, and N 1s X-ray photoelectron spectra were examined and the role of the ligand in their formation was elucidated. Based on the calculated multiplet splittings, numerous states were discerned in the Fe 2p spectra. This made it possible to reveal a correlation between the magnetic moment and some spectral parameters, such as the relative intensity and energy position of the satellites.
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页码：1614 / 1620
页数：6
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