Kinetics and Composition of Gaseous Products of Pyrolysis of Organometallic Complexes of Nickel, Iron, and Copper with Inorganic Anions

被引：0

作者：

Shmakov, A. G. ^{[1
]}

Paletsky, A. A. ^{[1
]}

Netskina, O. V. ^{[2
]}

Dmitruk, K. A. ^{[2
,3
]}

Komova, O. V. ^{[2
]}

Mukha, S. A. ^{[2
]}

机构：

[1] Russian Acad Sci, Voevodsky Inst Chem Kinet & Combust, Siberian Branch, Novosibirsk 630090, Russia

[2] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia

[3] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

COMBUSTION EXPLOSION AND SHOCK WAVES | 2024年 / 60卷 / 01期

关键词：

organometallic complexes; imidazole; iron oxide; nickel oxide; copper oxide; thermal decomposition kinetics; nanoscale materials; SOLUTION COMBUSTION SYNTHESIS; NI-BASED CATALYSTS; THERMAL-DECOMPOSITION; CRYSTAL-STRUCTURE; AMMONIUM-PERCHLORATE; NANOPARTICLES; IMIDAZOLE; BEHAVIOR; ETHYLENEDIAMINE; NANOCOMPOSITES;

D O I：

10.1134/S0010508224010040

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Organometallic complexes of transition metals with inorganic anions are considered as promising precursors for the synthesis of nanoscale materials used in various applications including chemical catalysis. In this work, organometallic complexes of nickel, iron, and copper with imidazole as an organic ligand and the nitrate anion as an inorganic ligand were synthesized and characterized. The kinetic parameters of thermal decomposition of the synthesized organometallic complexes were determined by low heating-rate thermogravimetric analysis and high-speed dynamic mass spectrometric thermal analysis. The main gaseous products of thermal decomposition of the complexes under high-speed heating were identified. The chemical and phase compositions of condensed combustion products of the organometallic complexes in air were studied.

引用

页码：25 / 41

页数：17

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