Solvent extraction of Os(IV) with 2-mercaptobenzothiazole into chloroform

被引:0
|
作者
T. M. Bahrainwala
Z. R. Turel
机构
[1] The Institute of Science,Nuclear Chemistry Division
关键词
Physical Chemistry; Inorganic Chemistry; Chloroform; Solvent Extraction; Acidic Medium;
D O I
暂无
中图分类号
学科分类号
摘要
2-mercaptobenzothiazole has been used for the solvent extraction of Os(IV) in acidic medium. The extraction of Os(IV) was found to be better than 90% over the pH range of 3.0 to 5.0 with an equilibration time of 5.0 minutes. The stoichiometry of metal:reagent determined by substoichiometric extraction and slope ratio method was found to be 1∶4. Decontamination factor for various elements in the substoichiometric extraction of Os(IV) were also evaluated.
引用
下载
收藏
页码:179 / 182
页数:3
相关论文
共 50 条
  • [41] MECHANISM OF 2-MERCAPTOBENZOTHIAZOLE REACTION WITH SULFENIAMIDES
    IGNATOV, VA
    ZHURNAL OBSHCHEI KHIMII, 1979, 49 (05): : 1122 - 1128
  • [42] Metabolism of 2-mercaptobenzothiazole by Rhodococcus rhodochrous
    Haroune, N
    Combourieu, B
    Besse, P
    Sancelme, M
    Kloepfer, A
    Reemtsma, T
    De Wever, H
    Delort, AM
    APPLIED AND ENVIRONMENTAL MICROBIOLOGY, 2004, 70 (10) : 6315 - 6319
  • [43] INVESTIGATIONS ON ELECTROCHEMICAL OXIDATION OF 2-MERCAPTOBENZOTHIAZOLE
    GOYAL, RN
    KUMAR, A
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1992, 31 (04): : 237 - 242
  • [44] Adsorption of 2-mercaptobenzothiazole onto pyrite
    Numata, Y
    Takahashi, K
    Liang, R
    Wakamatsu, T
    INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 1998, 53 (1-2) : 75 - 86
  • [45] Synthesis, Characterization and Antitumour Activity of Diorganotin (IV) Complexes Containing Silicon of 2-Mercaptobenzothiazole
    Liao, Qihua
    Lin, Sen
    Deng, Ruihong
    Huang, Zhiqiang
    Deng, Keyu
    Yan, Zhaohua
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2015, 35 (09) : 1923 - 1928
  • [46] Photodegradation of 2-mercaptobenzothiazole disulfide and related benzothiazoles
    Zajickova, Zuzana
    Parkanyi, Cyril
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2008, 45 (02) : 303 - 306
  • [47] STUDY OF PALLADIUM(II) COMPLEXING WITH 2-MERCAPTOBENZOTHIAZOLE
    KOLEVA, EG
    ALIMARIN, IP
    LOMAKINA, LN
    VESTNIK MOSKOVSKOGO UNIVERSITETA SERIYA 2 KHIMIYA, 1975, 16 (05): : 626 - 628
  • [48] Vibrational and normal coordinate analysis of 2-mercaptobenzothiazole
    Krishnakumar, V
    Ramaswamy, R
    Natarajan, A
    ASIAN JOURNAL OF CHEMISTRY, 2000, 12 (02) : 331 - 335
  • [49] ANAEROBIC DEGRADATION OF 2-MERCAPTOBENZOTHIAZOLE BY SULFUR BACTERIA
    KARELOVA, E
    TOMASOVICOVA, D
    BIOLOGIA, 1988, 43 (07) : 617 - 622
  • [50] ELECTROCHEMICAL OXIDATION OF 2-MERCAPTOBENZOTHIAZOLE AND 2-MERCAPTOBENZIMIDAZOLE
    BERGE, H
    MILLAT, H
    STRUBING, B
    ZEITSCHRIFT FUR CHEMIE, 1975, 15 (01): : 37 - 38