Reductive chlorination of bis(4-tert-butylphenyl)amine-N-oxyl nitroxyl radical

被引：0
|
作者：
V. A. Golubev
V. D. Sen’
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Russian Chemical Bulletin | 2013年 / 62卷
关键词：
nitroxyl radicals; oxoammonium salts; chlorination;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Unlike cyclic aliphatic nitroxyls, whose oxidation with halogens gives oxoammonium salts, bis(4-tert-butylphenyl)amine-N-oxyl (1) treated with chlorine undergoes reductive chlorination to the corresponding di- and trichlorodiphenylamines. Chlorine partially dealkylates the compounds obtained. Plausible mechanisms for these reactions were suggested.
引用
收藏
页码：2074 / 2078
页数：4
相关论文
共 50 条
  • [31] 3,5-Bis[5-(4-tert-butylphenyl)-1,3,4-oxadiazol-2-yl]nitrobenzene
    Osterod, F
    Kraft, A
    MOLECULES, 1999, 4 (10) : M114 - U16
  • [32] Reaction of bis[bis(trimethylsilyl)methyl]germylene with tris(4-tert-butylphenyl)methylium ion:: Formation of a unique germyl cation weakly σ-coordinated to aromatic group
    Ichinohe, M
    Hayata, Y
    Sekiguchi, A
    CHEMISTRY LETTERS, 2002, (10) : 1054 - 1055
  • [33] [5,10,15,20-Tetrakis(4-tert-butylphenyl)porphyrinato-κ4N]zinc(II) toluene solvate
    Slota, Rudolf
    Mele, Giuseppe
    Ejsmont, Krzysztof
    Domanski, Andrzej A.
    del Sole, Roberta
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M2582 - U1339
  • [34] Bis[1,2-bis(4-tert-butylphenyl)ethylene-1,2-dithiolato(1-)]nickel(II) pentane 0.25-solvate
    Das Gupta, Titir
    Applebaum, Jack
    Broussard, William
    Mack, Carson
    Wu, Che
    Mague, Joel T.
    Donahue, James P.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2023, 79 : 182 - +
  • [35] A low-band gap conductive copolymer of bis-3-hexylthiophene substituted 4-tert-butylphenyl quinoxaline and 3,4-ethylenedioxythiophene
    Ozyurt, Funda
    Durmus, Asuman
    Gunbas, E. Gorkem
    Toppare, Levent
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2010, 14 (02) : 279 - 283
  • [36] Metabolism of the stable nitroxyl radical 4-oxo-2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPONE)
    Kroll, C
    Borchert, HH
    EUROPEAN JOURNAL OF PHARMACEUTICAL SCIENCES, 1999, 8 (01) : 5 - 9
  • [37] Molecular structure of 9,10-bis[bis(4-tert-butylphenyl)methylene)-9,10-dihydroanthracene: A butterfly-shaped Thiele's hydrocarbon derivative
    Ko, Firyon
    Hirabayashi, Kazunori
    Shimizu, Toshio
    Sugiura, Ken-ichi
    TETRAHEDRON, 2019, 75 (03) : 357 - 362
  • [38] A low-band gap conductive copolymer of bis-3-hexylthiophene substituted 4-tert-butylphenyl quinoxaline and 3,4-ethylenedioxythiophene
    Funda Ozyurt
    Asuman Durmus
    E. Gorkem Gunbas
    Levent Toppare
    Journal of Solid State Electrochemistry, 2010, 14 : 279 - 283
  • [39] The EPR identification of bis(2,4,6-tri-tert-butylphenyl)-1,3-diphosphaallyl radical
    Alberti, A
    Benaglia, M
    Guerra, M
    Hudson, A
    Macciantelli, D
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1999, (08): : 1567 - 1568
  • [40] N-(4-tert-Butylphenyl)-N-phenyl-4-(9,10-diphenylanthracen-3-yl)benzenamine for blue organic light-emitting diodes
    Kim, Young Seok
    Kim, Dong Young
    Lee, Song Eun
    Kim, Young Kwan
    Yoon, Seung Soo
    JAPANESE JOURNAL OF APPLIED PHYSICS, 2016, 55 (06)
12345