Reductive chlorination of bis(4-tert-butylphenyl)amine-N-oxyl nitroxyl radical

被引：0
|
作者：
V. A. Golubev
V. D. Sen’
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Russian Chemical Bulletin | 2013年 / 62卷
关键词：
nitroxyl radicals; oxoammonium salts; chlorination;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Unlike cyclic aliphatic nitroxyls, whose oxidation with halogens gives oxoammonium salts, bis(4-tert-butylphenyl)amine-N-oxyl (1) treated with chlorine undergoes reductive chlorination to the corresponding di- and trichlorodiphenylamines. Chlorine partially dealkylates the compounds obtained. Plausible mechanisms for these reactions were suggested.
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页码：2074 / 2078
页数：4
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