Microwave assisted synthesis and characterization of novel metal-free and metallophthalocyanines containing four pyridyl groups

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作者
Zekeriya Bıyıklıoğlu
Halit Kantekin
机构
[1] Karadeniz Technical University,Department of Chemistry
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Phthalocyanine; DMAE; Phthalonitrile; Dicyano; Soret Region;
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摘要
The novel tetrasubstituted metal-free phthalocyanine (4) and metallophthalocyanines (5, 6, 7 and 8) bearing four pyridyl group moieties on peripheral positions have been synthesized by cyclotetramerization of the phthalonitrile derivative (3) in a multi-step reaction sequence. The new compounds were characterized by a combination of elemental analysis, 1H- and 13C-n.m.r., i.r., U.V.–vis and m.s. spectral data.
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页码:851 / 856
页数:5
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