Synthesis and molecular structures of dibenzo(perhydrotriazino)aza-14-crown-4 ethers

被引：0
|
作者：
Chyong Khong Khieu
A. T. Soldatenkov
An’ Le Tuan
A. N. Levov
A. F. Smol’yakov
V. N. Khrustalev
M. Yu. Antipin
机构：
[1] Russian University of Peoples’ Friendship,Hanoi University of Sciences
[2] Vietnam State University,Nesmeyanov Institute of Organoelemental Compounds
[3] Russian Academy of Sciences,undefined
来源：
Russian Journal of Organic Chemistry | 2011年 / 47卷
关键词：
Thiourea; Crown Ether; Compound IIIa; Triazine Ring; Azacrown Ether;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
By triple condensation of thiourea or guanidine with 1,ω-bis(2-formylphenoxy)-3-oxapentane and ammonium acetate first representatives of the new class of ethers bis(benzo)aza-14-crown-4 were obtained in 28–73% yield that included as a subunit a symm-perhydrotriazine ring. This reaction also proceeds readily with N-monomethyl- and N-monopropenyl-substituted thioureas affording the corresponding derivatives of triazinoazacrown ether. At the same time urea in the similar condensation does not form the expected perhydrotriazinoazacrown ether. The molecular structure of one perhydroazacrown ether as a complex with a chloroform molecule was established by XRD analysis.
引用
收藏
相关论文
共 50 条
  • [21] Synthesis of dibenzopiperidinoaza-14-crown-4 ethers and their one-step conversion into dibenzo-16-crown-3
    Levov, AN
    Strokina, VM
    Anh, LT
    Komarova, A
    Soldatenkov, AT
    Khrustalev, VN
    MENDELEEV COMMUNICATIONS, 2006, 16 (01) : 35 - 36
  • [22] Transformations of dibenzo(γ-oxopiperidino)aza-14-crowns-4 upon acylation.: Molecular structure of dibenzo-16-crown-3
    Levov, A. N.
    An, Le Tuan
    Soldatenkov, A. T.
    Khieu, Chyong Khong
    Khrustalev, V. N.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 44 (04) : 612 - 616
  • [23] Transformations of dibenzo(γ-oxopiperidino)aza-14-crowns-4 upon acylation. Molecular structure of dibenzo-16-crown-3
    A. N. Levov
    An’ Le Tuan
    A. T. Soldatenkov
    Chyong Khong Khieu
    V. N. Khrustalev
    Russian Journal of Organic Chemistry, 2008, 44 : 612 - 616
  • [24] SYNTHESIS AND STRUCTURAL STUDIES OF SODIUM COMPLEXES OF SYM-DIBENZO-14-CROWN-4 IONIZABLE LARIAT ETHERS
    BURNS, JH
    SACHLEBEN, RA
    INORGANIC CHEMISTRY, 1990, 29 (04) : 788 - 795
  • [25] N-Acylation and N-Alkylation of Bis(benzo)aza-14-Crown-4 Ethers. Novel Hybrid Compound - Bis(furanyl)triazinethiolazacrown Ether
    Hieu, Truong H.
    Komarova, Alexandra I.
    Levov, Alexander N.
    Soldatenkov, Anatoly T.
    Polyakova, Elena I.
    Nguyen, Tuyen V.
    Anh, Dang T. T.
    Nguyen, Dat T.
    Van, Tran T. T.
    Le Tuan Anh
    MACROHETEROCYCLES, 2018, 11 (04): : 438 - 441
  • [26] Synthesis of a new aza-14-crown-4 with di(α-pyridyl)-substituted bispidine subunit and the crystal structure of its complex with CoCl2
    Kolyadina, N. M.
    Sokol, V. I.
    Kvartalov, V. B.
    Davydov, V. V.
    Fomicheva, E. A.
    Soldatenkov, A. T.
    Sergienko, V. S.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (06) : 671 - 677
  • [27] Synthesis of geminal-substituted, sterically congested, proton-ionizable dibenzo-14-crown-4, dibenzo-16-crown-5, dibenzo-19-crown-6 and dibenzo-22-crown-7 lariat ethers
    Zhang, Dongmei
    Liu, Xiaodong
    Williams, Sharon L.
    Park, Chunkyung
    Bartsch, Richard A.
    ARKIVOC, 2010, : 38 - 57
  • [28] Synthesis of a new aza-14-crown-4 with di(α-pyridyl)-substituted bispidine subunit and the crystal structure of its complex with CoCl2
    N. M. Kolyadina
    V. I. Sokol
    V. B. Kvartalov
    V. V. Davydov
    E. A. Fomicheva
    A. T. Soldatenkov
    V. S. Sergienko
    Russian Journal of Inorganic Chemistry, 2013, 58 : 671 - 677
  • [29] Synthesis of new dibenzo-diaza-crown ethers
    Tetrahedron Lett, 13 (2213):
  • [30] A NOVEL METHOD FOR THE SYNTHESIS OF 4-NITRO-DIBENZO-14-CROWN-4
    CHEN, CS
    CHAO, HE
    WANG, SJ
    SYNTHETIC COMMUNICATIONS, 1987, 17 (12) : 1431 - 1434
12345