Synthesis and molecular structures of dibenzo(perhydrotriazino)aza-14-crown-4 ethers

被引：0
|
作者：
Chyong Khong Khieu
A. T. Soldatenkov
An’ Le Tuan
A. N. Levov
A. F. Smol’yakov
V. N. Khrustalev
M. Yu. Antipin
机构：
[1] Russian University of Peoples’ Friendship,Hanoi University of Sciences
[2] Vietnam State University,Nesmeyanov Institute of Organoelemental Compounds
[3] Russian Academy of Sciences,undefined
来源：
Russian Journal of Organic Chemistry | 2011年 / 47卷
关键词：
Thiourea; Crown Ether; Compound IIIa; Triazine Ring; Azacrown Ether;
D O I：
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摘要：
By triple condensation of thiourea or guanidine with 1,ω-bis(2-formylphenoxy)-3-oxapentane and ammonium acetate first representatives of the new class of ethers bis(benzo)aza-14-crown-4 were obtained in 28–73% yield that included as a subunit a symm-perhydrotriazine ring. This reaction also proceeds readily with N-monomethyl- and N-monopropenyl-substituted thioureas affording the corresponding derivatives of triazinoazacrown ether. At the same time urea in the similar condensation does not form the expected perhydrotriazinoazacrown ether. The molecular structure of one perhydroazacrown ether as a complex with a chloroform molecule was established by XRD analysis.
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