Dry reforming of methane on porous membrane catalytic systems

被引：0
|
作者：
M. V. Tsodikov
V. V. Teplyakov
A. S. Fedotov
N. Yu. Kozitsyna
V. Yu. Bychkov
V. N. Korchak
I. I. Moiseev
机构：
[1] Russian Academy of Sciences,A. V. Topchiev Institute of Petrochemical Synthesis
[2] Russian Academy of Sciences,N. S. Kurnakov Institute of General and Inorganic Chemistry
[3] Russian Academy of Sciences,N. N. Semenov Institute of Chemical Physics
来源：
Russian Chemical Bulletin | 2011年 / 60卷
关键词：
membrane catalytic systems; porous inorganic membranes kw]microreactor; syngas; dry methane reforming;
D O I：
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中图分类号：
学科分类号：
摘要：
A method of high-performance dry reforming of methane into syngas at temperatures below 650 °C on membrane catalytic systems was proposed. The membrane catalytic systems consist of porous inorganic membrane-supports, prepared by self-propagating high-temperature synthesis and modified by nanosized metallocomplex components, which are uniformly distributed inside membrane pores. The influence of the composition of the supported active components, temperature, and flow rate on the activity and selectivity of CH4 and CO2 transformations into syngas, as well as the dynamics of CH4 and CO2 conversion on the membrane catalytic systems were studied.
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页码：55 / 62
页数：7
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