Synthesis and Characterization of a New (E, E)-Dioxime and Its Homo and Heteronuclear Complexes Containing Macrobicylic Moieties

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作者
Duralí Mendíl
Ahmet Bílgín
Yaşar Gök
H. Basrí Şentük
机构
[1] Karadeniz Technical University,Department of Chemistry
关键词
BF; -capped complex; cobalt(III) complex; diazatetraoxamacrobicycle; (E, E)-Dioxime; heterotrinuclear complex; template effect;
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摘要
A new N,N'-substituted diaminoglyoxime (H2L) containing a diazatetraoxamacrobicycle [2.2.2B] has been synthesized from an aromatic primary amine attached to the cryptand moiety and cyanogen-di-N-oxide. The BF2+-capped Co(III) and heterotri-nuclear complexes of thevic-dioxime were prepared. The new compounds werecharacterized by a combination of elemental analysis and 1H NMR,13C NMR, IR and MS spectral data.
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页码:265 / 270
页数:5
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