Vibrational spectroscopy investigation of the structure of multicomponent phosphorus-containing silicate glasses

被引：0
|
作者：
S. V. Mulevanov
N. I. Min’ko
S. A. Kemenov
A. A. Osipov
V. N. Bykov
机构：
[1] V. G. Shukhov Belgorod State Technological University,
[2] Institute of Mineralogy of the Ural Branch of the Russian Academy of Sciences of the Russian Federation,undefined
来源：
Glass and Ceramics | 2009年 / 66卷
关键词：
silicate glasses; phosphorus additives; structure; vibrational spectroscopy;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
IR spectroscopy and Raman scattering have been used to study the structure of multicomponent silicate glass with phosphorus oxide addition, simulating the commercial compositions of container glass and sheet float-glass. It is established that P2O5 addition gives a micro-nonuniform structure consisting of silicon oxide anionic groupings, with different degrees of connectedness, and orthophosphate groupings. Such nonuniformity promotes subsequent liquation and crystallization of multicomponent glasses containing phosphorus.
引用
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页码：117 / 119
页数：2
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