Vibrational spectroscopy investigation of the structure of multicomponent phosphorus-containing silicate glasses

被引：9
|
作者：
Mulevanov, S. V. [1 ]
Min'ko, N. I. [1 ]
Kemenov, S. A. [1 ]
Osipov, A. A. [2 ]
Bykov, V. N. [2 ]
机构：
[1] VG Shukhov Belgorod State Technol Univ, Belgorod, Russia
[2] Russian Acad Sci Russian Federat, Ural Branch, Inst Mineral, Miass, Chelyabinsk Obl, Russia
来源：
GLASS AND CERAMICS | 2009年 / 66卷 / 3-4期
关键词：
silicate glasses; phosphorus additives; structure; vibrational spectroscopy;
D O I：
10.1007/s10717-009-9137-3
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
IR spectroscopy and Raman scattering have been used to study the structure of multicomponent silicate glass with phosphorus oxide addition, simulating the commercial compositions of container glass and sheet float-glass. It is established that P(2)O(5) addition gives a micro-nonuniform structure consisting of silicon oxide anionic groupings, with different degrees of connectedness, and orthophosphate groupings. Such nonuniformity promotes subsequent liquation and crystallization of multicomponent glasses containing phosphorus.
引用
收藏
页码：117 / 119
页数：3
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