Ribbed-monofunctionalized iron(II) clathrochelate with tert-butyl sulfide substituents: Synthesis, structure, and thermochemical transformations

被引：0
|
作者：
P. A. Petrov
A. V. Virovets
P. E. Plyusnin
E. Yu. Filatov
I. V. El’tsov
Ya. Z. Voloshin
S. N. Konchenko
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
[2] Novosibirsk National State Research University,Nesmeyanov Institute of Organoelement Compounds
[3] Russian Academy of Sciences,undefined
来源：
Russian Journal of Inorganic Chemistry | 2014年 / 59卷
关键词：
Tert; Boron Neutron Capture Therapy; Iron Nitride; Iron Borate; Cage Complex;
D O I：
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摘要：
A ribbed-monofunctionalized macrobicyclic iron(II) complex with tert-butyl sulfide substituents has been prepared via nucleophilic substitution of its dichloroclathrochelate precursor with tert-butylthiolate ion. This new complex has been characterized using elemental analysis, IR and multinuclear NMR spectroscopy, and the single crystal X-ray diffraction. Its thermal destruction occurs with release of isobutylene and polyunsaturated hydrocarbons giving iron borate, iron fluoropolyborate, and iron nitride as follows from combined thermal analysis and X-ray powder diffraction data.
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页码：1162 / 1167
页数：5
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