Partial Oxidation of Dimethoxymethane to Syngas Over Supported Noble Metal Catalysts

被引：0
|
作者：
S. D. Badmaev
N. O. Akhmetov
V. A. Sobyanin
机构：
[1] Boreskov Institute of Catalysis,
[2] Novosibirsk State University,undefined
来源：
Topics in Catalysis | 2020年 / 63卷
关键词：
Dimethoxymethane; Partial oxidation; Syngas production; Noble metal catalyst; Pt; SOFC;
D O I：
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学科分类号：
摘要：
Catalytic partial oxidation (PO) of dimethoxymethane (DMM) to syngas was investigated in a fixed-bed continuous flow reactor under ambient pressure and at 250–500 °C over Pt-, Rh- and Ru-supported on Ce0.75Zr0.25O2–δ catalysts. The Pt catalyst was found to be the most active and selective. It provided complete conversion of DMM to gas mixture containing ˃ 60 vol% of H2 and CO at 400 °C, GHSV = 10,000 h−1 using a reaction mixture: DMM:O2:N2 = 28.6:14.3:57.1 (vol%).
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页码：196 / 202
页数：6
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