Partial oxidation of ethane to syngas over supported metal catalysts

被引：3
|
作者：
Liu, SL [1 ]
Xiong, GX [1 ]
Yang, WS [1 ]
Xu, LY [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2000年 / 70卷 / 02期
关键词：
supported metal; high temperatures;
D O I：
10.1023/A:1010397001697
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The reaction performance for C2H6-O-2 to syngas over different supported metal catalysts was investigated in a flow-reactor. The activated behavior of ethane is different from that of methane over the supported nickel catalysts. Although there may exist a gas phase reaction at high temperatures, over a Ni (or Rh)/gamma -Al2O3 catalyst, the partial oxidation of ethane to syngas is a heterogeneous process, while over a Pt (or Pd)/gamma -Al2O3 catalyst, it may be a home-heterogeneous process. The Ni/gamma -Al2O3 and Rh/gamma -Al2O3 catalysts are suitable for partial oxidation of ethane to syngas at high temperatures.
引用
收藏
页码：311 / 317
页数：7
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