Oxidative N-nitration of secondary amines

被引：0

作者：

O. V. Anikin

G. V. Pokhvisneva

D. L. Lipilin

A. V. Mezhenin

V. A. Tartakovsky

机构：

[1] Russian Academy of Sciences,N. D. Zelinsky Institute of Organic Chemistry

来源：

Russian Chemical Bulletin | 2009年 / 58卷

关键词：

secondary amines; nitrites; diacetoxyiodobenzene; oxidative nitration; -nitroamines; -nitrosoamines;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Reaction of secondary amines with the nitrite anion assisted by diacetoxyiodobenzene results in respective N-nitroamines. It is the first example of oxidative nitration of the amino group. N-Nitrosoamines are by-products. The yields and the ratio of the nitration and nitrosation products depend on the nature of the starting amine, cation of the salt used, and the solvent.

引用

页码：2043 / 2046

页数：3

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