Kinetics and mechanism of the deep electrochemical oxidation of sodium diclofenac on a boron-doped diamond electrode

被引:0
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作者
M. D. Vedenyapina
D. A. Borisova
K. -H. Rosenwinkel
D. Weichgrebe
P. Stopp
A. A. Vedenyapin
机构
[1] Zelinsky Institute of Organic Chemistry of Russian Academy of Sciences,Institute of Sanitary Engineering & Waste Management
[2] Leibniz University,undefined
关键词
diclofenac; boron doped diamond electrode; electrolysis; cyclic voltammetry;
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摘要
The kinetics and mechanism of the deep oxidation of sodium diclofenac on a boron-doped diamond electrode are studied to develop a technique for purifying wastewater from pharmaceutical products. The products of sodium diclofenac electrolysis are analyzed using cyclic voltammetry and nuclear magnetic resonance techniques. It is shown that the toxicity of the drug and products of its electrolysis decreases upon its deep oxidation.
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页码:1393 / 1396
页数:3
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