Kinetics and mechanism of the deep electrochemical oxidation of sodium diclofenac on a boron-doped diamond electrode

被引：6
|
作者：
Vedenyapina, M. D. [1 ]
Borisova, D. A. [1 ]
Rosenwinkel, K. -H. [2 ]
Weichgrebe, D. [2 ]
Stopp, P. [2 ]
Vedenyapin, A. A. [1 ]
机构：
[1] Zelinsky Inst Organ Chem Russian Acad Sci, Moscow 119991, Russia
[2] Leibniz Univ Hannover, Inst Sanit Engn & Waste Management, D-30167 Hannover, Germany
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2013年 / 87卷 / 08期
关键词：
diclofenac; boron doped diamond electrode; electrolysis; cyclic voltammetry; WALL CARBON NANOTUBES; DEGRADATION; IDENTIFICATION; REMOVAL; FATE;
D O I：
10.1134/S0036024413080268
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics and mechanism of the deep oxidation of sodium diclofenac on a boron-doped diamond electrode are studied to develop a technique for purifying wastewater from pharmaceutical products. The products of sodium diclofenac electrolysis are analyzed using cyclic voltammetry and nuclear magnetic resonance techniques. It is shown that the toxicity of the drug and products of its electrolysis decreases upon its deep oxidation.
引用
收藏
页码：1393 / 1396
页数：4
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