Crystal structure of a novel binuclear Cu(II) complex Cu2[(Dmbiim)4H2O](ClO4)4·3H2O

被引：0
|
作者：
P. Yang
Y. Li
C. Yin
X. Gao
机构：
[1] Shanxi University,Institute of Molecular Science, Key Laboratory of Chemical Biology and Molecular Engineering of Ministry of Education
来源：
Journal of Structural Chemistry | 2005年 / 46卷
关键词：
binuclear complex compound; copper;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A novel complex, Cu2[(Dmbiim)4H2O](ClO4)4·3H2O (Dmbiim = 1.1′-dimethyl-2.2′-biimida-zole), has been synthesized and studied by X-ray crystallography. Crystal data for CuO9N8C16Cl2H22: a = 10.160(2) Å, b = 12.991(3) Å, c = 20.646(4) Å, β = 101.443(3)°, space group P2(1)/c, Z = 4, dcalc = 1.504 g/cm3, R = 0.0718. The crystal structure reveals that the complex is cage-shaped, with two Cu ions bridged by Dmbiim and each Cu ion chelated by the oxygen atom of water and four nitrogen atoms of Dmbiim.
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页码：761 / 764
页数：3
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