Synthesis and Structural Characterization of [Cu2(μ-dppa)2(tptz)2](ClO4)2•3H2O

被引：3
|
作者：
Xu, Hong-wu [1 ]
Zhang, Liu-xue [1 ]
Li, Yin-hua [1 ]
Wang, Hong-fang [1 ]
机构：
[1] Zhongyuan Univ Technol, Dept Mat & Chem Engn, Zhengzhou 450007, Henan, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2011年 / 41卷 / 07期
关键词：
copper(I); dppa; tptz; x-ray crystallography; CARBONYL-COMPLEXES; CRYSTAL-STRUCTURE; 2,4,6-TRIS(2-PYRIDYL)-1,3,5-TRIAZINE; COORDINATION; DESIGN; BINDING; TPTZ;
D O I：
10.1080/15533174.2011.591297
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[Cu-2(mu-dppa)(2)(tptz)(2)](ClO4)(2)center dot 3H(2)O was synthesized by self-assembly with dppa, Cu(I) salt, and tptz in solution (dppa = bis(diphenylphosphino)acetylene, tptz = 2,4,6-tris(2'-pyridyl)-1,3,5-triazine) and characterized by x-ray diffraction, elemental analysis, H-1-nuclear magnetic resonance (NMR) spectra, and P-31-NMR spectra. The complex crystallizes in triclinic space group P-1 with a = 11.2202(5) angstrom, b = 12.5231(6) angstrom, c = 16.9294(8) angstrom, alpha = 105.9860(10)degrees, beta = 108.7270(10)degrees, gamma = 91.1730(10)degrees, V = 2150.18(17) angstrom(3), and Z = 4.
引用
收藏
页码：743 / 745
页数：3
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