The Passerini three-component reaction of aldehyde end-functionalized polymers via RAFT polymerization using chain transfer agents featuring aldehyde

被引：0
|
作者：
Ryohei Kakuchi
Yamato Okura
机构：
[1] Gunma University,Division of Molecular Science, Faculty of Science and Technology
来源：
Polymer Journal | 2020年 / 52卷
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摘要：
In this study, a novel pyrazole–carbodithioate-based chain transfer agent (CTA) featuring an aldehyde group (CTA-CHO) was designed and synthesized for RAFT polymerization. The obtained CTA-CHO was employed for the RAFT polymerization of styrene to afford well-defined polystyrenes bearing an aldehyde at their chain ends with low Ð values (~1.1). In addition, the reactivity of the aldehyde moiety at the end of the chain was precisely evaluated, while the Passerini three-component reaction was successfully performed on the aldehyde group.
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页码：1057 / 1066
页数：9
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