Geochemistry of gas and water discharge from the magmatic-hydrothermal system of Guallatiri volcano, northern Chile

This work presents the first chemical and isotopic (δ13C-CO2, δ13C-CH4, 3He, 4He, 20Ne, 40Ar, 36Ar, δ18O, and δD) data for fluid discharges from Guallatiri volcano, a remote and massive stratovolcano, which is considered as the second most active volcano of the Central Volcanic Zone (CVZ) in northern Chile. Fumarolic gases had outlet temperatures of between 80.2 and 265 °C, and showed a significant magmatic fluid contribution marked by the occurrence of SO2, HCl, and HF that are partially scrubbed by a hydrothermal aquifer. The helium isotope ratios (< 3.2) were relatively low compared to those of other active volcanoes in CVZ, possibly due to contamination of the magmatic source by 4He-rich crust and/or crustal fluid addition to the hydrothermal reservoir. Geothermometry in the H2O-CO2-CO-H2-CH4 system suggests equilibrium temperatures of up to 320 °C attained in a vapor phase at redox conditions intermediate between those typical of hydrothermal and magmatic environments. Thermal springs located 12 km northwest of the volcano’s summit had outlet temperatures of up to 50.1 °C, neutral to slightly basic pH, and a sodium bicarbonate composition, typical of distal fluid discharges in volcanic systems. Cold springs at the base of the volcanic edifice, showing a calcium sulfate composition, were likely produced by interaction of shallow meteoric water with CO2- and H2S-rich gases. A geochemical conceptual model was constructed to graphically represent these results, which can be used as an indication for future geochemical monitoring and volcanic hazard assessment.