Thermal Expansion of Ni3S2 in Ni3S2-Ni Alloys

被引：0
|
作者：
A. D. Vershinin
E. N. Selivanov
R. I. Gulyaeva
N. I. Sel’menskikh
机构：
[1] Russian Academy of Sciences,Institute of Metallurgy, Ural Division
来源：
Inorganic Materials | 2005年 / 41卷
关键词：
Copper; Nickel; Sulfide; Hexagonal; Thermal Expansion;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The thermal expansion of nickel sulfide in Ni3S2-Ni alloys (a sample synthesized in this work and a commercial Ni3S2-Ni-Cu9S5 converter matte) is measured using high-temperature x-ray diffraction. The best fit equations are derived for the temperature-dependent (≤980 K) parameters of the rhombohedral (hexagonal) and cubic cells of nickel sulfide, and the thermal expansion coefficients of Ni3S2 are determined. The results demonstrate that the thermal expansion of Ni3S2 is influenced by impurity phases: Ni metal and Cu9S5. The chemical strain arising from the dissolution of the copper sulfide in Ni3S2 cancels out the shear strain near the polymorphic transformation.
引用
收藏
页码：882 / 887
页数：5
相关论文
共 50 条
  • [31] Ultrafast Alkaline Ni/Zn Battery Based on Ni-Foam-Supported Ni3S2 Nanosheets
    Hu, Pu
    Wang, Tianshi
    Zhao, Jingwen
    Zhang, Chuanjian
    Ma, Jun
    Du, Huiping
    Wang, Xiaogang
    Cui, Guanglei
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (48) : 26396 - 26399
  • [32] Regulating Complex Transition Metal Oxyhydroxides Using Ni3S2: 3D NiCoFe(oxy)hydroxide/Ni3S2/Ni Foam for an Efficient Alkaline Oxygen Evolution Reaction
    Fan, Yating
    Shi, Weidong
    Li, Longhua
    [J]. INORGANIC CHEMISTRY, 2023, 62 (04) : 1561 - 1569
  • [33] Engineering FeOOH/Ni(OH)2 heterostructures on Ni3S2 surface to enhance seawater splitting
    Yang, Chen
    Li, Ya-Dong
    Cao, Li-Juan
    Wang, Xi-Long
    Liang, Han-Pu
    [J]. RARE METALS, 2024, 43 (05) : 1989 - 1998
  • [34] Engineering FeOOH/Ni(OH)2 heterostructures on Ni3S2 surface to enhance seawater splitting
    Chen Yang
    Ya-Dong Li
    Li-Juan Cao
    Xi-Long Wang
    Han-Pu Liang
    [J]. Rare Metals, 2024, 43 : 1989 - 1998
  • [35] ETUDE QUALITATIVE ET CINETIQUE DUN PROCESSUS DOXYDATION DU SULFURE DE NICKEL NI3S2 SUIVANT - NI3S2 + 1/202 - NI0 + 2 NIS
    ABEGG, JL
    [J]. BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1961, (12): : 2210 - &
  • [36] PRECIPITATION OF Ni3S2 FROM SULFATE SOLUTIONS.
    Okuwaki, Akitsugu
    Kanome, Osamu
    Okabe, Taijiro
    [J]. 1600, (15 B):
  • [37] Heazlewoodite, Ni3S2: An electroactive material for supercapacitor application
    Kumar, Mohit
    Jeong, Dong In
    Sarwar, Nasir
    Yoon, Dae Ho
    [J]. CERAMICS INTERNATIONAL, 2021, 47 (12) : 16852 - 16860
  • [38] DETERMINATION OF HEAT EFFECT OF ANODIC PROCESS OF Ni3S2
    Zhang
    Fang
    [J]. Transactions of Nonferrous Metals Society of China, 1994, (02) : 14 - 17
  • [39] AN ELECTROCHEMICAL STUDY OF THE BACTERIAL LEACHING OF SYNTHETIC NI3S2
    VERBAAN, B
    HUBERTS, R
    [J]. INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 1988, 24 (3-4) : 185 - 202
  • [40] STUDIES OF MECHANISM OF POLYCYTHEMIA INDUCED IN RATS BY NI3S2
    SOLYMOSS, B
    JASMIN, G
    [J]. EXPERIMENTAL HEMATOLOGY, 1978, 6 (01) : 43 - 47
12345