Phase transitions of the NASICON-type mixed phosphates LiM2(PO4)3 (M = Ti, Zr) and LiInNb(PO4)3

被引：0
|
作者：
I. Yu. Pinus
A. R. Shaikhlislamova
I. A. Stenina
N. A. Zhuravlev
A. B. Yaroslavtsev
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] Russian Academy of Sciences,Institute of Solid State Chemistry, Ural Division
来源：
Inorganic Materials | 2009年 / 45卷
关键词：
Phase Transition; Thermal Hysteresis; Zirconium Phosphate; Nuclear Magnetic Resonance Line; Cation Mobility;
D O I：
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摘要：
The structural phase transitions of LiTi2(PO4)3, LiInNb(PO4)3, and LiZr2(PO4)3 have been studied by X-ray diffraction, impedance spectroscopy, 7Li NMR spectroscopy, and calorimetry. The results indicate that, as the temperature is raised, the lithium ions in the structure of LiTi2(PO4)3 and LiInNb(PO4)3 redistribute between the M1 and M2 sites. The thermal expansion coefficients along the crystallographic axes of LiTi2(PO4)3 and LiInNb(PO4)3 are estimated.
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页码：1370 / 1374
页数：4
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