Phase transitions of the NASICON-type mixed phosphates LiM2(PO4)3 (M = Ti, Zr) and LiInNb(PO4)3

被引：5
|
作者：
Pinus, I. Yu. [1 ]
Shaikhlislamova, A. R. [1 ]
Stenina, I. A. [1 ]
Zhuravlev, N. A. [2 ]
Yaroslavtsev, A. B. [1 ]
机构：
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
[2] Russian Acad Sci, Inst Solid State Chem, Ural Div, Ekaterinburg 620041, Russia
来源：
INORGANIC MATERIALS | 2009年 / 45卷 / 12期
基金：
俄罗斯基础研究基金会;
关键词：
CONDUCTIVITY; LIZR2(PO4)3; TRANSPORT;
D O I：
10.1134/S0020168509120127
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The structural phase transitions of LiTi2(PO4)(3), LiInNb(PO4)(3), and LiZr2(PO4)(3) have been studied by X-ray diffraction, impedance spectroscopy, Li-7 NMR spectroscopy, and calorimetry. The results indicate that, as the temperature is raised, the lithium ions in the structure of LiTi2(PO4)(3) and LiInNb(PO4)(3) redistribute between the M1 and M2 sites. The thermal expansion coefficients along the crystallographic axes of LiTi2(PO4)(3) and LiInNb(PO4)(3) are estimated.
引用
收藏
页码：1370 / 1374
页数：5
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