The Study of Acid Leaching on the Mineralogical and Microscopic Changes of Red Mud

When alumina is extracted from bauxite ore, one of the environmental pollutants created is known as red mud (RM). This study clarifies that the RM obtained from the Iran Alumina Company has a significant proportion of iron oxides (24%), alumina (19%), silica (17%), and calcium (21%), as well as trace amounts of other minerals. The elements in the RM can be removed and utilized again to reduce environmental pollution. Acid leaching is one of the best ways to selectively exclude some minerals from the RM. In this research, the RM is exposed to different inorganic acids, including HCl, HNO3, H2SO4, and H3PO4, and their binary mixtures. By comparing the results obtained from XRD, EDX, and SEM, it was discovered that CaSO4 crystals are formed by exposing the RM to sulfuric acid. Besides, phosphoric acid was only able to destroy the surface of RM particles. The XRD analyses of acid-washed residues demonstrated that except for the residue of HCl 5 N, all residues contain hematite, showing that inorganic acids cannot easily extract hematite from the complex phases of red mud. While the dissolution of RM with HCl or HNO3 will remove most of the calcium content of RM texture, increasing its iron oxide percentage, which may subsequently be utilized to make colors and pigments.