Crystal structure of μ-hydroxo-bis(2-aminoethyl)aminedicopper(II) perchlorate

被引：0
|
作者：
Duan C.-Y. [1 ]
Lu Z.-L. [1 ]
You X.-Z. [1 ]
Mak T.C.W. [2 ]
机构：
[1] Coordination Chemistry Institute, State Key Lab. of Coord. Chemistry, Nanjing University, Nanjing
[2] Department of Chemistry, Chinese University of Hong Kong
来源：
Transition Metal Chemistry | 1997年 / 23卷 / 1期
关键词：
Bipy; Tren; Title Complex; Dicopper; Amine Nitrogen Atom;
D O I：
10.1023/A:1006962118958
中图分类号：
学科分类号：
摘要：
A novel, high-symmetry dicopper complex bridged by only a single hydroxo has been synthesized and structurally characterized. The coordination geometry of copper(II) is a strict trigonal bipyramidal of C3v symmetry. The three equivalent amino nitrogen atoms of the ligand form the equatorial plane, while the tripodal nitrogen atom and the hydroxo anion occupy axial positions. The bridging Cu - (OH) - Cu angle of the single hydroxo anion is only 136.5°, which does not agree well with data found in similar compounds. The magnetic-structural relation is discussed.
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页码：77 / 79
页数：2
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